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Fluoroalkyl end-capped betaine-type cooligomeric nanocomposites-immobilized palladium nanoparticles were prepared by the reactions of palladium chloride with sodium acetate in the presence of sodium chloride and the corresponding fluorinated cooligomers. Outer blocks of poly(2,3,4,5,6-pentafluorostyrene)-containing ABA-triblock copolymeric nanocomposites-immobilized palladium nanoparticles were prepared by the use of the corresponding block copolymers under similar conditions. TEM images showed that palladium nanoparticles can be immobilized outside the fluorinated cooligomeric nanocomposite cores; in contrast, palladium nanoparticles can be effectively immobilized inside these fluorinated ABA-triblock copolymeric nanocomposite cores. Thus, these two different fluorinated copolymers enabled the controlled immobilization of palladium nanoparticles in the fluorinated nanocomposite cores. These fluorinated nanocomposites-immobilized palladium nanoparticles were also applied to the catalysts for Suzuki-Miyaura cross-coupling reaction, and the different reactivity between these nanocomposites was observed.
Original languageEnglish
JournalColloid and Polymer Science
Publication date2012
Volume290
Issue7
Pages589-597
ISSN0303-402X
DOIs
StatePublished
CitationsWeb of Science® Times Cited: 1

Keywords

  • Fluorinated betaine-type cooligomeric nanoparticles , Fluorinated triblock copolymer, Palladium nanoparticles, Nanocomposites, Controlled immobilization, Suzuki–Miyaura cross-coupling reaction
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