Characterization of La0.995Ca0.005NbO4/Ni anode functional layer by electrophoretic deposition in a La0.995Ca0.005NbO4 electrolyte based PCFC
Publication: Research - peer-review › Conference article – Annual report year: 2011
The Electrophoretic Deposition (EPD) technique has been applied to the preparation of a porous La0.995Ca0.005NbO4/Ni composite anode layer, deposited on a porous pre-sintered La0.995Ca0.005NbO4/Ni support. Powders of La0.995Ca0.005NbO4 and NiO were suspended in a solution of acetylacetone, iodine and water. Selectivity in the composition of the deposited layer was analyzed as a function of the suspension compositions and deposition conditions. A quasi-symmetrical cell was produced by depositing La0.995Ca0.005NbO4 electrolyte layer on the anode layer by EPD, and by applying a porous La0.995Ca0.005NbO4/Ni counter electrode on the dense electrolyte layer by brushing. The performance of the electrodes was evaluated by electrochemical impedance spectroscopy in 3% wet H2.
|Journal||International Journal of Hydrogen Energy|
|Workshop||7th Petite Workshop on the Defect Chemical Nature of Energy Materials|
|Period||14/05/11 → 17/05/11|
|Citations||Web of Science® Times Cited: 4|
- Ca-doped LaNbO4, Electrochemical characterization, Solid oxide fuel cells, Electrophoretic co-deposition, Anode functional layer, Selectivity analysis
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