catena-Poly[tetrasodium [[cis-dioxidotrans-bis(sulfato-kappaO)molybdate(VI)]-my-sulfato-kappaO:O']]

Publication: Research - peer-reviewJournal article – Annual report year: 2008

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Single crystals of the title compound, {Na4[MoVIO2(SO4)3]}n, were grown from a melt of MoO3 and Na2SO4 in Na2S2O7. In contrast to the structure of the isoformular K compound, K4[MoVIO2(SO4)3], with its monomeric anion, this sodium analogue contains a polymeric anion of the type {[MoVIO2(SO4)2--(SO4)]4}n. The MoVI cations, surrounded by two tightly bonded O atoms and four O atoms of one bridging and two terminal sulfato ligands, form zigzag chains parallel to [100]. All four Na+ cations are situated between the anionic chains and have distorted octahedral coordination spheres.
Original languageEnglish
JournalActa Crystallographica. Section E: Structure Reports Online
Publication date2008
Volumee64
Pagesi73
ISSN1600-5368
DOIs
StatePublished
CitationsWeb of Science® Times Cited: 1
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