An experimental and kinetic modeling study of premixed nitromethane flames at low pressure

Publication: Research - peer-reviewJournal article – Annual report year: 2011

Standard

An experimental and kinetic modeling study of premixed nitromethane flames at low pressure. / Zhang, Kuiwen; Li, Yuyang; Yuan, Tao; Cai, Jianghuai; Glarborg, Peter; Qi, Fei.

In: Proceedings of the Combustion Institute, Vol. 33, No. 1, 2011, p. 407-414.

Publication: Research - peer-reviewJournal article – Annual report year: 2011

Harvard

APA

CBE

MLA

Vancouver

Author

Zhang, Kuiwen; Li, Yuyang; Yuan, Tao; Cai, Jianghuai; Glarborg, Peter; Qi, Fei / An experimental and kinetic modeling study of premixed nitromethane flames at low pressure.

In: Proceedings of the Combustion Institute, Vol. 33, No. 1, 2011, p. 407-414.

Publication: Research - peer-reviewJournal article – Annual report year: 2011

Bibtex

@article{ba93b7d19aad4488aca21605282832c6,
title = "An experimental and kinetic modeling study of premixed nitromethane flames at low pressure",
publisher = "Elsevier Inc.",
author = "Kuiwen Zhang and Yuyang Li and Tao Yuan and Jianghuai Cai and Peter Glarborg and Fei Qi",
year = "2011",
doi = "10.1016/j.proci.2010.06.002",
volume = "33",
number = "1",
pages = "407--414",
journal = "Proceedings of the Combustion Institute",
issn = "1540-7489",

}

RIS

TY - JOUR

T1 - An experimental and kinetic modeling study of premixed nitromethane flames at low pressure

A1 - Zhang,Kuiwen

A1 - Li,Yuyang

A1 - Yuan,Tao

A1 - Cai,Jianghuai

A1 - Glarborg,Peter

A1 - Qi,Fei

AU - Zhang,Kuiwen

AU - Li,Yuyang

AU - Yuan,Tao

AU - Cai,Jianghuai

AU - Glarborg,Peter

AU - Qi,Fei

PB - Elsevier Inc.

PY - 2011

Y1 - 2011

N2 - An experimental and modeling study is reported on three premixed nitromethane/oxygen/argon flames at low pressure (4.655kPa) with equivalence ratios (ϕ) of 1.0, 1.5 and 2.0. Flame species were identified with tunable synchrotron vacuum ultraviolet photoionization. The mole fraction profiles of more than 30 species including intermediates and radicals were obtained by near-threshold burner scan with selected photon energies. With a Pt–6%Rh/Pt–30%Rh thermocouple, the flame temperature profiles were measured. A detailed kinetic mechanism with 88 species and 701 reactions was proposed and validated against experimental results of all three flames. The computed predictions showed satisfactory agreement with the experimental results. Based on a rate-of-production analysis, reaction pathway diagrams were obtained to describe the hydrocarbon oxidation process and nitrogenous species chemistry in the nitromethane flame with ϕ=1.5.

AB - An experimental and modeling study is reported on three premixed nitromethane/oxygen/argon flames at low pressure (4.655kPa) with equivalence ratios (ϕ) of 1.0, 1.5 and 2.0. Flame species were identified with tunable synchrotron vacuum ultraviolet photoionization. The mole fraction profiles of more than 30 species including intermediates and radicals were obtained by near-threshold burner scan with selected photon energies. With a Pt–6%Rh/Pt–30%Rh thermocouple, the flame temperature profiles were measured. A detailed kinetic mechanism with 88 species and 701 reactions was proposed and validated against experimental results of all three flames. The computed predictions showed satisfactory agreement with the experimental results. Based on a rate-of-production analysis, reaction pathway diagrams were obtained to describe the hydrocarbon oxidation process and nitrogenous species chemistry in the nitromethane flame with ϕ=1.5.

KW - Kinetic modeling

KW - Premixed flame

KW - Nitromethane

U2 - 10.1016/j.proci.2010.06.002

DO - 10.1016/j.proci.2010.06.002

JO - Proceedings of the Combustion Institute

JF - Proceedings of the Combustion Institute

SN - 1540-7489

IS - 1

VL - 33

SP - 407

EP - 414

ER -